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📡 Protein Science · Method

Surface Plasmon Resonance (SPR)

Real-time binding kinetics
🎯 Difficulty ★★★ Advanced Duration About 1–2 days 🎯 Use Quantify protein-ligand binding, determine affinity KD and on/off rates
📖 Principle
Binding changes refractive index at chip surface; SPR monitors this in real time for affinity and kinetics
Below are 4 steps. Open each to see how to do it and add products to your shared list.

📋 Workflow

Full workflow, products add-to-cart directly
1

Ligand immobilization

1 h
Immobilize ligand protein on CM5 or other sensor chip by amine coupling or capture
💡 Tip Moderate immobilization avoids mass transport limitation
⚠️ Caution Ligand must be high-purity and stable
🧪 Materials for this step (click to shop by spec/brand)
2

Analyte gradient

30 min
Prepare series concentration of analyte (flow) for binding kinetics
💡 Tip Concentration range spans KD
⚠️ Caution Dilute analyte in matching buffer
🧪 Materials for this step (click to shop by spec/brand)
3

Binding-dissociation measurement

2–4 h
Inject analytes sequentially to record association, then buffer to observe dissociation
💡 Tip Add regeneration for multi-cycle measurements
⚠️ Caution Constant temperature for reliable kinetics
🧪 Materials for this step (click to shop by spec/brand)
4

Kinetic fitting

1 h
Fit sensorgrams to a 1:1 model with software, calculate ka, kd and equilibrium KD
💡 Tip Assess residuals to validate model
⚠️ Caution Global fitting across concentrations is more reliable
🧪 Materials for this step (click to shop by spec/brand)

⚠️ 5 Common Beginner Mistakes

  • Over-immobilization causes mass transport limitation
  • Buffer mismatch causes non-specific binding
  • Air bubbles distort sensorgrams
  • Insufficient concentration range hampers fitting
  • Temperature instability drifts kinetics

❓ FAQ

+Can SPR measure KD? Precision?
Yes, SPR measures ka/kd in real time to compute KD, a gold standard for interaction quantification.
+How to choose immobilization?
Capture/directed for small molecules, amine coupling for proteins; control active site carefully.
+What's needed for small molecules?
Need high-sensitivity SPR system capable of small molecules and high-quality ligand.

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Data authenticity: Product categories from JW Supply Chain standard taxonomy; method→step→product connected. Last updated: 2026-08-23 · v3.0