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🎯 Spectrometry / MS · Method

MS

Mass & identification
🎯 Difficulty ★★★ Advanced Duration About 3–6 h 🎯 Use Molecular weight determination, structural identification and trace quantitation
📖 Principle
Ions are separated by mass-to-charge ratio in electric/magnetic fields and detected to form a mass spectrum
Below are 5 steps. Open each to see how to do it and add products to your shared list.

📋 Workflow

Full workflow, products add-to-cart directly
1

Tune & calibration

30 min
Tune the MS and calibrate the mass axis with calibration solution
💡 Tip Periodically verify mass accuracy
⚠️ Caution Keep the ion source clean
🧪 Materials for this step (click to shop by spec/brand)
2

Sample prep

30 min
Dilute the sample to a suitable concentration in the mobile phase/solvent
💡 Tip Remove salts/lipids to avoid ion suppression
⚠️ Caution Use internal standard to correct ion suppression
🧪 Materials for this step (click to shop by spec/brand)
3

MS method development

30 min
Set ionization mode, source temperature and monitored ion transitions
💡 Tip MRM improves selectivity
⚠️ Caution Avoid source temperature that causes in-source decomposition
🧪 Materials for this step (click to shop by spec/brand)
4

Injection & acquisition

40 min
Inject blank, standards and samples; acquire mass spectral data
💡 Tip Gradient elution improves peak shape
⚠️ Caution Avoid carryover contamination
🧪 Materials for this step (click to shop by spec/brand)
5

Data & quant

30 min
Integrate peaks, quantify by internal standard and report
💡 Tip Isotope internal standard is most accurate
⚠️ Caution Confirm no interference on MRM transitions
🧪 Materials for this step (click to shop by spec/brand)

⚠️ 5 Common Beginner Mistakes

  • Ion suppression lowering results
  • Matrix contamination lowering sensitivity
  • Mass axis drift affecting accuracy
  • Carryover causing false positives
  • Poor cleaning contaminating the source

❓ FAQ

+Why internal standard?
Corrects ion suppression and prep losses.
+ESI or APCI?
ESI for polar/bio molecules; APCI for non-polar small molecules.
+MRM vs full scan?
MRM has better selectivity, lower noise, higher sensitivity.

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Data authenticity: Product categories from JW Supply Chain standard taxonomy; method→step→product connected. Last updated: 2026-08-23 · v3.0