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🔬 Chromatography · Method

HPLC

Column separation & quant
🎯 Difficulty ★★☆ Medium Duration About 2–4 h 🎯 Use Separation and quantification of components in pharmaceutical, food, environmental and chemical samples
📖 Principle
Components partition between stationary and mobile phases to separate, then are quantified by a detector
Below are 5 steps. Open each to see how to do it and add products to your shared list.

📋 Workflow

Full workflow, products add-to-cart directly
1

Mobile phase prep

20 min
Mix ultrapure water with organic solvent at the target ratio, degas by sonication and filter
💡 Tip Use degassed mobile phase to avoid baseline noise
⚠️ Caution Keep organic phase ratio consistent
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2

Standard & sample prep

30 min
Dissolve standards and samples in mobile phase to suitable concentration and filter
💡 Tip Prepare external standard calibration curve
⚠️ Caution Filter samples before injection to remove particulates
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3

Column equilibration

30 min
Flush the column with mobile phase until baseline stabilizes
💡 Tip Equilibrate for at least 10 column volumes
⚠️ Caution Purge lines when changing mobile phase
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4

Method setup & injection

20 min
Set flow rate, column temperature and detection wavelength; inject blank, standards and samples
💡 Tip Run in isocratic or gradient mode
⚠️ Caution Avoid overpressure that damages the column
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5

Data processing & quant

30 min
Integrate peak areas and calculate sample concentration using the calibration curve
💡 Tip Use at least 5-6 calibration points
⚠️ Caution Check retention time drift
🧪 Materials for this step (click to shop by spec/brand)

⚠️ 5 Common Beginner Mistakes

  • Non-degassed mobile phase causing baseline spikes
  • Unfiltered samples clogging the column
  • Too few calibration points causing quant bias
  • Not addressing abnormal pressure increase
  • Wrong wavelength reducing sensitivity

❓ FAQ

+Why HPLC-grade solvents?
Low impurities avoid ghost peaks interfering with quantitation.
+What if pressure rises?
Back-flush or replace the inlet frit; replace the column if needed.
+Isocratic or gradient?
Use isocratic for few components; gradient for wide polarity differences.

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Data authenticity: Product categories from JW Supply Chain standard taxonomy; method→step→product connected. Last updated: 2026-08-23 · v3.0